Topics in Stereochemistry, Volume 25Scott E. Denmark, Jay A. Siegel John Wiley & Sons, 2006 M04 27 - 368 pages Topics in Stereochemistry, previously edited by "the father of stereochemistry" Ernest L. Eliel, is a longstanding, successful series covering the most important advances in the field. The much-anticipated Volume 25 includes chapters on the following topics: * Stereochemistry of Molecules in Inclusion Crystals * Torsional Motion of Stilbene-type Molecules in Crystals * Supramolecular Networks of Porphyrins * Homo- and Heterochirality in Crystals * Supramolecular Synthesis of 1D Chains and 2D Layers in Hydrogen Bond Networks of Ureas and 2-D Pyrimidinones * Chiral Auxiliaries Powerful for Both Enantioresolution and Determination of Absolutely Stereochemistry by X-Ray Crystallograph * Engineering Stereospecific Reactoins in Crystals: Synthesis of Compounds with Adjacent Stereogenic Quaternary Centers by Photodecarbonylation of Crystalline Ketones * The CH/ Hydrogen Bond: An Important Molecular Force in Controlling the Crystal Conformation of Organic Compounds and Three-Dimensional Structure of Biopolymers * Stereoselective Thermal Solid-State Reactions * Crystal Structures and Functionalities of Platinum (II) Complexes Controlled by Various Intermolecular Interactions |
Contents
| 1 | |
2 TORSIONAL MOTION OF STILBENETYPE MOLECULES IN CRYSTALS | 31 |
3 SUPRAMOLECULAR NETWORKS OF PORPHYRINS | 49 |
4 HOMO AND HETEROCHIRALITY IN CRYSTALS | 81 |
5 SUPRAMOLECULAR SYNTHESIS OF 1D CHAINS AND 2D LAYERS IN HYDROGEN BOND NETWORKS OF UREAS AND 2PYRIMIDINON... | 135 |
6 CHIRAL AUXILIARIES POWERFUL FOR BOTH ENANTIOMER RESOLUTION AND DETERMINATION OF ABSOLUTE CONFIGURATION... | 177 |
7 ENGINEERING STEREOSPECIFIC REACTIONS IN CRYSTALS SYNTHESIS OF COMPOUNDS WITH ADJACENT STEREOGENIC QUATER... | 205 |
8 THE CHHYDROGEN BOND AN IMPORTANT MOLECULAR FORCE IN CONTROLLING THE CRYSTAL CONFORMATION OF ORGANIC C... | 255 |
9 STEREOSELECTIVE THERMAL SOLIDSTATE REACTIONS | 303 |
10 CRYSTAL STRUCTURES AND FUNCTIONALITIES OF PLATINUMII COMPLEXES CONTROLLED BY VARIOUS INTERMOLECULAR IN... | 351 |
| 375 | |
| 391 | |
CUMULATIVE TITLE INDEX VOLUMES 125 | 397 |
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Common terms and phrases
absolute configuration achiral acid Acta Crystallogr Angew aromatic asymmetric atoms axial carboxylic carboxylic acids chains Chem chiral auxiliary COOH coordination coordination polymers crystal engineering crystal packing crystal structure crystalline CSD refcode decarbonylation Desiraju determined diastereomeric dimer enantiomerically enantiomers enantiopure enantioselective ester Figure formation Garcia-Garibay H/EA Harada heterochiral homochiral HPLC hydrogen bonds inclusion complex Inorg interactions intermolecular ions irradiation isomers Kaupp ketone Kostyanovsky lattice ligands metal method methyl mixture molecular molecules networks Nishio obtained optically active Organic pedal motion Perkin Trans Ph Ph Ph phase phenyl photochemical Phys platinum(II polymers porphyrin pyrimidinone racemic compound radical reactant reaction cavity reactions in crystals reactivity ring salts Scheme single crystals solid state reactions solution solvent space group stabilizing stacking Stereochemistry stereoselective stereospecific substituents Supramolecular Chemistry synthesis synthon Tanaka Tetrahedron Lett urea X-ray crystal conformation X-ray crystal structure yield
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